By Hill Jr C.G.
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Additional info for An introduction to chemical engineering kinetics & reactor design
The algebraic sum of the exponents is called the total order or overall order of the reaction. 7. If one considers a system in which both forward and reverse reactions are important, the net rate of reaction can generally be expressed as the difference between the rate in the forward direction f and that in the opposite direction f. 1 Reaction Orders The manner in which the reaction rate varies with the concentrations of the reactants and products is indicated by stating the order of the reaction.
1 Mathematical Characterization of Simple Reaction Systems rate is proportional to the product of the concentrations of two different species. 12 for £* and employing basic stoichiometric relations. + When the stoichiometric coefficients of species A and B are identical and when one starts with equal concentrations of these species, the Class II rate expression will collapse to the Class I form because, under these conditions, one can always say that CA = CB. 16 leads to the following relation.
Over what range of pressures may carbon deposit on the catalyst? Over what range of pressures will it not deposit? Note. Assume that only the reactions given in the table occur, and that equilibrium is attained. 58 For an initial ratio of CO 2 to H 2 of unity, what must the pressure be if exactly 30% of the carbon present in the feed can precipitate as solid carbon? The equilibrium constants are based on a standard state of unit fugacity for the gaseous species and on a standard state corresponding to the pure solid for carbon.
An introduction to chemical engineering kinetics & reactor design by Hill Jr C.G.